This isn't the reason they break. I did some analysis and wrote up a big sticky on Greenhulk on this topic. These valves always fail at the weld joint. For those that don't know, these valves are made by a friction welding process, where they use an alloy of one material for the valve head, and a different alloy for the stem. It is cheaper to do this than making them from a large bar.
The alloys they use to make them from corrodes very easily, and even more so once heated to a high temp. If you look at the weld joint area of the exhaust valves in an engine with broken valve(s), you will see lots of corrosion pitting right at the weld joint area. These engines always have 100% humidity in the exhaust chamber, and you will notice that most (not all) of the failures are on valves in the rear-most cylinder, which runs the valves the hottest, and is closer to the waterbox.
On these alloys, corrosion pitting leads to tunneling/microcracking, which eventually grows into a full crack, and off pops the head of the valve, right at the weld joint. This is because the weld joint is more vunerable to embrittlement, so microcracking can spread easier into a full-blown crack.
The later valves are made from Inconel, which is both corrosion-resistant, and tougher. It tends to bend rather than break.
The consensus is if you always fog (correctly fog) before any extended storage, you lessen the possibility of this happening.
Also, most of the failures are on the higher HP (SC) engines, which runs the valves hotter.