Nope... PB blaster isn't going to work since the bolt isn't really stuck, and the threads ar about 1/4 below that block. (It would never get down into the threds) Also... It's just tight because there is a gasket behind it. When ever you work on PWC carbs... you HAVE TO use a hand impact to remove those screws... or... you twist the Philips socket.
You could still try to use a hand impact since there is still a little of the Philips head in it. BUT... I would probably just drill the head off. Once the head comes off, you can get the block off... and then what's left of the bolt, sticking up, should be able to un-thread.
If you go the impact route... I recommend putting a little cardboard on the work bench. It helps hold the carb... and will protect it from the impact. (Makes clean up easy too)